Perhaps you're not … It is the yin to baking soda's yang, meaning it is acidic, while baking soda is basic. Baking powder does the same thing, and is just a combination of bicarb with cream of tartar. When in a recipe together, the two react to help the food rise. Why your muffins are collapsing, I don't know. You can make your own baking powder: simply mix two parts cream of tartar with one part bicarbonate of soda. You can make your own baking powder: simply mix two parts cream of tartar with one part bicarbonate of soda. The substitution is to use 1 teaspoon of baking powder for each 5/8 teaspoons cream of tartar and 1/4 teaspoon baking soda. When it’s exposed to liquid and heat, carbon dioxide gas is formed, which causes baked goods to rise ( 2 ). If cream of tartar is used along with baking soda in a cake or cookie recipe, omit both and use baking powder instead. And baking powder is typically made of 2 parts baking Cream of Tartar Substitution - The answer is, there is not a good substitution. You see, many biscuit doughs are made with baking powder as the leavening agent. Baking powder, which contains bicarbonate of soda, comes pre-mixed with the acidic ingredient for you – so all you need to add is the moisture. Cream of tartar has more of a stabilizing effect than baking soda, and each serves a different purpose in baking. If cream of tartar is used in a cookie recipe, it's used with baking soda to form a type of double-acting baking powder. The reason why that’s so is that baking soda is made of tartaric acid and sodium bicarbonate, also known as cream of tartar and baking soda, respectively. As it comes pre-mixed with the acidic ingredient for you, all you need to add is the moisture. Baking soda (a base), cream of tartar (an acid) and corn starch (the filler) are three common ingredients. Baking Power if a mixture of the 3, generally an acid, a base and a filler. The acidic ingredient most often used in baking powder is cream of tartar. Baking powder is made up of several elements, one of these being sodium bicarbonate, as well as an acid, cream of tartar and filler like cornflour to absorb any moisture. Cream of tartar, or potassium bitartrate, is a by-product of the process of making wine. In fact, baking powder is a combination of baking soda and cream of tartar. While baking soda (sodium bicarbonate) and cream of tartar (potassium bitartrate) are chemically similar and serve similar functions for health and household purposes, they are technically not the same thing. soda, also known as sodium bicarbonate, has the chemical formula NaHCO3. (Bicarb needs an acid to activate itself and cream of tartar, which is actually potassium bitartrate, does the job.) Cream of tartar also known as tartrate salt, has the formula KHC4H4O6. 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